A point is all Manchester City need to win Group F, while Hoffenheim aim to end their debut campaign in memorable fashion.
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Shakhtar Donetsk and Lyon both have Group F's second qualification berth in their sights in Ukraine.
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Benfica will be looking to finish Group E positively while AEK Athens are out to avoid a clean sweep of defeats.
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Viktoria Plzeň are playing for third place, and UEFA Europa League football, against Group G runners-up Roma.
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Liverpool and Napoli face a matchday six showdown, the Italian side travelling to Anfield with the upper hand in Group C.
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Barcelona have already won Group B, with final opponents Tottenham hoping to join them in the round of 16.
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Monaco are hoping to end a long winless run as they bow out against Dortmund, the last side they beat in Europe.
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Atlético Madrid will seek to secure first place in Group A away to Club Brugge, who are sure to finish third.
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Porto will finish first in Group D regardless of the result in Istanbul, with Galatasaray chasing third place.
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Paris will reach the knockout rounds with victory away to Crvena zvezda, who have their sights set on the UEFA Europa League.
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Inter are bidding to finish second in Group B as they conclude their campaign at home to eliminated PSV Eindhoven.
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Secure in second place, Schalke round off Group D with a visit from Lokomotiv Moskva, who are aiming to snatch third.
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"The most intelligent player in the world." Luka Modrić is now a Ballon d'Or winner.
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